| # | Date | Promotion | Match |
| 1 | 09.02.2010 |  |
Rey Mysterio defeats CM Punk (14:53) WWE Friday Night SmackDown #547 - TV-Show @ Baton Rouge River Center in Baton Rouge, Louisiana, USA |
| 2 | 21.02.2010 |  |
World Heavyweight Title Elimination Chamber: Chris Jericho defeats CM Punk and John Morrison and R-Truth and Rey Mysterio and The Undertaker (c) (35:35) - TITLE CHANGE !!! WWE Elimination Chamber 2010 - Pay Per View @ Scottrade Center in St. Louis, Missouri, USA |
| 3 | 02.03.2010 | |
Rey Mysterio defeats Luke Gallows (11:15) WWE Friday Night SmackDown #550 - TV-Show @ Intrust Bank Arena in Wichita, Kansas, USA |
| 4 | 16.03.2010 | |
Luke Gallows defeats Rey Mysterio (8:57) WWE Friday Night SmackDown #552 - TV-Show @ Staples Center in Los Angeles, California, USA |
| 5 | 28.03.2010 | |
Rey Mysterio defeats CM Punk (6:28) WWE WrestleMania XXVI - "Get All Fired Up" - Pay Per View @ University Of Phoenix Stadium in Glendale, Arizona, USA |
| 6 | 13.04.2010 | |
Rey Mysterio & The Hart Dynasty (David Hart Smith & Tyson Kidd) defeat CM Punk, Darren Young & Luke Gallows (13:20) WWE Friday Night SmackDown #556 - TV-Show @ o2 Arena in London, England, UK |
| 7 | 19.04.2010 |  |
Edge, Rey Mysterio & Triple H defeat Chris Jericho, CM Punk & Luke Gallows (10:59) WWE Monday Night RAW #882 - TV-Show @ Izod Center in East Rutherford, New Jersey, USA |
| 8 | 20.04.2010 | |
CM Punk & Luke Gallows defeat Kane & Rey Mysterio (10:34) WWE Friday Night SmackDown #557 - TV-Show @ Mohegan Sun Arena in Uncasville, Connecticut, USA |
| 9 | 25.04.2010 | |
CM Punk defeats Rey Mysterio (15:57) WWE Extreme Rules 2010 - Pay Per View @ 1st Mariner Arena in Baltimore, Maryland, USA |
| 10 | 27.04.2010 | |
Montel Vontavious Porter & Rey Mysterio defeat CM Punk & Luke Gallows (5:06) WWE Friday Night SmackDown #558 - TV-Show @ Giant Center in Hershey, Pennsylvania, USA |
| 11 | 11.05.2010 | |
Rey Mysterio defeats CM Punk by DQ (10:35) WWE Friday Night SmackDown #560 - TV-Show @ HSBC Arena in Buffalo, New York, USA |
| 12 | 18.05.2010 | |
Montel Vontavious Porter & Rey Mysterio defeat CM Punk & Luke Gallows (10:30) WWE Friday Night SmackDown #561 - TV-Show @ Scotiabank Place in Ottawa, Ontario, Canada |
| 13 | 23.05.2010 | |
S.E.S. Pledge Vs. Hair: Rey Mysterio defeats CM Punk (13:49) WWE Over The Limit 2010 - Pay Per View @ Joe Louis Arena in Detroit, Michigan, USA |
| 14 | 01.06.2010 | |
World Heavyweight Title #1 Contendership 16 Man Battle Royal: Rey Mysterio defeats Caylen Croft and Chavo Guerrero and Chris Masters and Christian and Curt Hawkins and Dolph Ziggler and Drew McIntyre and Finlay and JTG and Kane and Kofi Kingston and Luke Gallows and Montel Vontavious Porter and Trent Barreta and Vance Archer (19:39) WWE Friday Night SmackDown #563 - TV-Show @ American Airlines Center in Dallas, Texas, USA |
| 15 | 15.06.2010 | |
Rey Mysterio & The Big Show defeat CM Punk & Jack Swagger (9:48) WWE Friday Night SmackDown #565 - TV-Show @ RBC Center in Raleigh, North Carolina, USA |
| 16 | 20.06.2010 | |
World Heavyweight Title Fatal Four Way: Rey Mysterio defeats CM Punk and Jack Swagger (c) and The Big Show (10:27) - TITLE CHANGE !!! WWE Fatal 4-Way - Pay Per View @ Nassau Veterans Memorial Coliseum in Uniondale, New York, USA |
